I check this for you and looks like you successfully added Payoneer account as your payment method, it will become active on February 4th.
For security reasons, every new payment method will become active in three calendar days. You can read more about it in this help article.
Once your payment method becomes active, you'll be able to withdraw the available funds from your Upwork account to your payment method by using the Get Paid Now button under the Available tab or by going to your Settings> Get Paid and click Get Paid Now.
Let us know if you need any further assistance.