I did it before many times and it was very quick. Sometimes as quick as 5 minutes, but usually around 10 to 15 minutes.
I haven't done it for a year now, but I tried it this afternoon (it's 5PM where I am now) and I am still waiting for the money to show up on Payoneer. Did something change in the service?
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I thought within a few minutes to a few hours depending on various factors. If you aren't getting an error, give it a little time. Of course double check both your Upwork and Payoneer information that its up-to-date. Have a great day!